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We have not seen any zanpakuto that have multiple unrelated elements in the manga (Hitsugaya & Rukia are snow-ice types, but they are very closely related and could be consider the same thing). In the anime, replacement captain Amagai had both fire and lightning powers in Bankai, but he is not a canon character. Also, in the games Jushiro Ukitake's zanpakuto has both water and lightning elements, but this is not what his actual zanpakuto abilities are (it was revealed after the games were released). So thus far there is no canon character with multiple unrelated elements.

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