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Sado: he has the power of strength.. when he first had his powers he was protecting Ichigo's sister Karin, while being attacked by an Hollow. Orihime : she has the power of rejecting reality ( comment by Aizen ) she first had her powers when she was protecting her fellow classmates and her best friend Tatsuki, also while being attacked by an Hollow.

Both of them got their powers from the Hougyoku.

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